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Hydrogen Sulfide (H₂S)

Hydrogen Sulfide, H₂S is a highly toxic gas that has a distinctive and unpleasant rotten-egg smell. It is a colorless gas, that can occur naturally in the air via various crude or natural oil sources, volcanic gases, and spring waters. Trace amounts of H₂S can be found in the atmosphere which is generally not harmful.
Hydrogen Sulfidein the Environment
Hydrogen Sulfide is produced by bacterial breakage of animal, plant, and human waste. It can be produced by volcanic gases, and natural springs as well. H₂S gas dissolved in the soil helps in the root growth of plants.

DO YOU KNOW?

The primary target organ of hydrogen sulfide poisoning is the respiratory system. Once inhaled, hydrogen sulfide is quickly absorbed by the lungs. This may result in cardiac arrest or even death since it affects the neurological and cardiac tissues. The most well-known symptom of hydrogen sulfide poisoning is sudden death among sewage workers. All exposures to H₂S should be avoided because they have severe harmful effects. - Saiyed, H N. Indian Journal of Medical Research; New Delhi

Sources of Hydrogen Sulphide Gas

Hydrogen sulphide gas is produced naturally from decaying organic matter and industrial processes, and can be lethal in high concentrations. Following are some of its potential sources:

Natural Sources

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Volcanic Gases

During volcanic activity, volcanoes naturally release H2S gas through their vents and cracks.

Gas wells

H2S gas may be present in natural gas wells and could be released during production and drilling.

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Natural Gas Reservoirs

It may be present in natural gas reservoirs, and can be discharged during processing and extraction.

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Natural Springs

As sulfur-containing minerals react with water to produce H2S gas, natural springs can be a source of H2S gas.

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Crude Petroleum

Crude petroleum may produce H2S gas during extraction and processing, posing health and safety issues.

Industrial Sources

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Sewage Treatment

From the decomposition of the organic content in wastewater, sewage treatment plants might emit H2S gas.

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Refineries

Refineries can generate H2S gas by the processing of sulphur-containing crude oil. The gas can pose threat to ones health and safety.

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Kraft Paper Mills

In the pulping process, kraft paper mills use chemicals based on sulphur, which produces H2S gas as a byproduct

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Food Processing

Food processing units that utilize sulphurs and sulphuric acid emit H2S gas into the surrounding environment.

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Wastewater Treatment

Wastewater treatment plants produce H2S gas during the breakdown of organic matter.

Hydrogen Sulfidein the Environment
H2S is extremely hazardous for workers, laborers, miners, etc. that have to work with this gas continuously, on a regular basis. It is a highly flammable gas and can react with steel at ambient temperature. This makes handling, storage, transportation, and working with the gas very laborious and demanding.

H₂S Exposure Effects Chart

*As per BUREAU OF INDIAN STANDARDS

10 PPM

15 min

-

>15 min

-

>1h-4h

Eye irritation

>4-8ht

Maximum tolerable concentration for prolonged exposure

50-100 PPM

15 min

Loss of olfactory perception

>15 min

Eye irritation

>1h-4h

Eye and bronchial irritation

>4-8ht

Serious respiratory distress and asthenia

150-250 PPM

15 min

Eye and skin irritation

>15 min

Eye and bronchial irritation

>1h-4h

Serious respiratory distress and asthenia

>4-8ht

Danger in case of continuous exposure

300-400 PPM

15 min

Loss of olfactory perception eye

>15 min

Severe respiratory distress acute asthenia

>1h-4h

Pulmonary edema & risk of death

>4-8ht

Pulmonary edema & risk of death

500-1,000 PPM

15 min

Loss of consciousness respiratory distress

>15 min

Risk of pulmonary edema and death

>1h-4h

-

>4-8ht

-

>1,000 PPM

All durations:

Immediate loss of consciousness and respiratory distress

*As per BUREAU OF INDIAN STANDARDS

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